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Stoichiometry of Reaction Heats

Since enthalpy is an extensive property, the quantity of heat obtained from a reaction will depend on the amounts of reactants.  The same methods used to solve stoichiometry problems can be used with thermochemical equations.  Essentially  what we do is to treat the quantity of heat as if it were a quantity of a reactant or product. Consider the following example.

What is the enthalpy change associated with the formation of 95.6 g of HCl(g) in the reaction?

H2(g) + Cl2(g) ==> HCl(g) H = -184.6 kJ

Solution

The calculation involves converting grams of HCl to moles of HCl, and then to kilojoules of heat.

       
1 mol HCl
 
-184.6 kJ
   
H
=
95.6 g  HCl
x
---------------
x
-----------------
=
484 kJ
       
36.46 g HCl
 
1 mol HCl
   






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