Thermochemical Equations
A thermochemical equation is the chemical equation for a reaction including
phase labels, with the enthalpy of reaction shown immediately after the equation.
In a thermochemical equation the coefficients represent moles and can therefore
be fractional. The following is an example
H2(g) + 1/2 O2(g) ==> H2O(g)
H
= -286 kJ
In working with thermochemical equations you will find the following rules
helpful.
- When a thermochemical equation is multiplied by a factor, the value
of
H for the new
equation is obtained by multiplying the value of
H
by the same factor.
- When a chemical equation is reversed, the sign of
H
is reversed.
- If two thermochemical equations can be added to obtain a third equation,
the enthalpy of the third equation will be the sum of the enthalpies of the
first two reactions.
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